Thermodynamical Properties of Inhomogeneous Associating Fluids Using Density Functions
Thermodynamical Properties of Inhomogeneous Asscociating Fluids Using Density Function
Pradeep Kumar Chowdhury
Department of Physics, R. D. S. College, B. R. A. Bihar University
Muzaffrapur 842002, Bihar, India
ABSTRACT An Analytical expression for molecular association on the phase coexistence properties of fluid with one or two direction attractive centre is discussed .The basic theory of Rosenfeld for the hard sphere is extended to inhomogeneous fluids on the basis of density function. The density functional approach in the grand canonical ensemble utilized to determine thermo dynamical properties of the inhomogeneous fluids. The theoretical prediction is in good quantitative agreement with the simulation result which is available